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(9,10‐Dihydroxyoctadecyl)ammonium: A Structurally Unique Class of Clay Intercalable Surfactants
Author(s) -
Jankovič Luboš,
Kronek Juraj,
Madejová Jana,
Hronský Viktor
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500169
Subject(s) - chemistry , montmorillonite , thermogravimetric analysis , alkyl , thermal stability , nuclear magnetic resonance spectroscopy , infrared spectroscopy , crystallography , oleylamine , inorganic chemistry , polymer chemistry , organic chemistry , chemical engineering , nanoparticle , engineering
The structurally unique clay–intercalable (9,10‐dihydroxyoctadecyl)trimethylammonium (OH‐ODTMA) cationic surfactant was synthesized in two steps from commercially available oleylamine. Sodium montmorillonite was modified by a cation‐exchange reaction by using three different octadecyltrimethylamonium ODTMA‐based organic cations. Basal spacings, surfactant configuration, the interlamellar structure, and the thermal stability of the resulting organomontmorillonites were characterized by using X‐ray diffraction, IR spectroscopy, thermogravimetric analysis, and NMR spectroscopy techniques. Magic‐angle spinning 13 C NMR spectroscopy demonstrated the coexistence of ordered (all‐ trans ) and disordered ( gauche ) alkyl chain conformations. Deconvolution of the NMR spectra indicated that the conformational ordering of the surfactant molecules within the gallery of montmorillonite strongly depended on their orientation, the presence of functional groups, and the temperature. Relative to that found in ODTMA‐MT, the amount of gauche conformers was significantly higher in montmorillonite intercalated with the OH‐ODTMA cation and higher than that in the synthetic precursor, the oleyltrimethylammonium cation. Changes in the ordering of the organic cations were confirmed by FTIR spectroscopy with a distinct frequency shift in the CH stretching and overtone bands. The novel alkylammonium surfactant functionalized with two OH groups in the middle of the backbone represents a prospective ingredient for organoclay–polyurethane nanocomposites.