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Synthesis, Structure, and Reactivity of Ruthenium(0) Indane Complexes fac ‐[Ru(NCMe) 3 (CO) 2 (InX 3 )] (X = Cl, Br)
Author(s) -
Itazaki Masumi,
Ito Masaki,
Nakazawa Hiroshi
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500112
Subject(s) - chemistry , ruthenium , acetonitrile , indane , reactivity (psychology) , medicinal chemistry , crystal structure , molar ratio , stereochemistry , crystallography , catalysis , organic chemistry , medicine , alternative medicine , pathology
The first ruthenium indane complexes, fac ‐[Ru(NCMe) 3 (CO) 2 (InX 3 )] (X = Cl: 1 , Br: 2 ), were synthesized in the reaction of triruthenium dodecacarbonyl Ru 3 (CO) 12 with 3 equiv. of InX 3 in acetonitrile at 80 °C for 30 min. Reaction of fac ‐[Ru(NCMe) 3 (CO) 2 (InX 3 )] (X = Cl: 1 , Br: 2 ) with PPh 3 at a 1:1 molar ratio in acetonitrile at 50 °C for 5 h afforded cis , cis , trans ‐[Ru(NCMe) 2 (CO) 2 (InX 3 )(PPh 3 )] (X = Cl: 3 , Br: 4 ). The structures of 1 – 4 were determined by using single‐crystal X‐ray analysis.
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