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Thermally Stable Four‐Coordinate Silicon(IV) Complexes with an Si=N Double Bond and an SiN 3 El Skeleton (El = O, S, Se, Te)
Author(s) -
Mück Felix M.,
Ulmer Anna,
Baus Johannes A.,
Burschka Christian,
Tacke Reinhold
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201500083
Subject(s) - chemistry , silylene , silicon , crystallography , double bond , solid state , crystal structure , skeleton (computer programming) , stereochemistry , polymer chemistry , organic chemistry , computer science , programming language
The donor‐stabilized silylene 1 reacts with N 2 O and PhElElPh (El = S, Se, Te) to form the respective silicon(IV) complexes 2 – 5 with an Si=N double bond. Compounds 2 – 5 were structurally characterized by crystal structure analyses and NMR spectroscopic studies in the solid state and in solution.