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Electronic and Steric Effects of the Peripheral Substitution in Deca‐ and Undecaaryl Metallocorroles (Eur. J. Inorg. Chem. 2/2014)
Author(s) -
Gao Di,
Canard Gabriel,
Giorgi Michel,
Vanloot Pierre,
Balaban Teodor Silviu
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201490005
Subject(s) - steric effects , chemistry , copper , electrochemistry , cover (algebra) , aryl , peripheral , planar , stereochemistry , electrode , organic chemistry , engineering , mechanical engineering , computer science , alkyl , computer graphics (images) , operating system
The cover picture shows the saddling that occurs in copper corroles. This saddling is reinforced by bulky peripheral aryl groups, which modulate the electrochemical properties of deca‐ and undecaaryl copper corroles. On the other hand, the corresponding cobalt corroles remain essentially planar in spite of the steric peripheral congestion. Details are discussed in the article by G. Canard et al. on p. 279 ff . For more on the story behind the cover research, see the Cover Profile .