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A Mn 6 Cluster inside a Mn 10 Wheel: Characterization of a Mn 16 ‐Oximate Complex Resulting from a Tetrazole‐2‐pyridylketoneoximate Ligand
Author(s) -
Alcazar Laura,
FontBardia Mercè,
Escuer Albert
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201403128
Subject(s) - chemistry , manganese , tetrazole , ligand (biochemistry) , azide , cluster (spacecraft) , crystallography , characterization (materials science) , medicinal chemistry , stereochemistry , receptor , nanotechnology , organic chemistry , biochemistry , materials science , computer science , programming language
A new Mn 16 topology consisting of one hexanuclear {Mn II 2 Mn III 4 } unit coordinated inside a decametallic {Mn II 6 Mn III 2 Mn IV 2 } wheel was synthesized from 2‐pyridylcyanoxime and azido ligands. A new tetrazole‐2‐pyridylketoneoximate ligand was obtained in situ by cyclization of the cyano group and azide mediated by manganese cations.