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Synthesis and Characterization of ortho ‐Thio‐Functionalized Triarylmethyl Palladium Complexes
Author(s) -
Schöler Stephan,
Merz Klaus,
Puls Arik,
Winter Manuela,
Dyker Gerald
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402908
Subject(s) - palladium , chemistry , thio , intramolecular force , ligand (biochemistry) , stereochemistry , organic chemistry , catalysis , receptor , biochemistry
A series of triarylmethyl palladium complexes with ortho coordination sites were synthesized. Thereby, the palladium atom exhibits various inter‐ and intramolecular binding modes towards the organic ligand. Further, the first crystallographically proven, exclusively σ‐coordinated triarylmethyl palladium complexes, stabilized by ortho ‐thio‐substituents, were discovered. The NMR spectra of the palladium complexes indicate temperature‐dependent dynamic behavior.