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Hybrid Material Constructed from Hg(NCS) 2 and 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT): Coordination of TPymT in a 2,2′‐Bipyridine‐Like Mode
Author(s) -
Safin Damir A.,
Holmberg Rebecca J.,
Burgess Kevin M. N.,
Robeyns Koen,
Bryce David L.,
Murugesu Muralee
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402832
Subject(s) - chemistry , bipyridine , tris , stoichiometry , 1,3,5 triazine , triazine , coordination polymer , polymer chemistry , coordination complex , 2,2' bipyridine , polymer , inorganic chemistry , organic chemistry , crystal structure , metal , biochemistry
A unique Hg II coordination polymer has been synthesized through the reaction of 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) with a stoichiometric mixture of HgCl 2 and NH 4 NCS, thus leading to the formation of a 1D polymeric heteroleptic hybrid material [{Hg(NCS) 2 } 2 TPymT] n ( 1 ). Two coordination pockets of TPymT in 1 are each coordinated to two Hg II cations in an unprecedented 2,2′‐bipyridine‐like mode.