Activation of a 1‐Chlorophosphirane Complex by Aluminum Trichloride: Generation and Trapping of [Fc‐P‐W(CO) 5 ] (Fc = Ferrocenyl) | Zendy

Ho Feny | Zendy; Ganguly Rakesh | Zendy; Mathey François | Zendy

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Activation of a 1‐Chlorophosphirane Complex by Aluminum Trichloride: Generation and Trapping of [Fc‐P‐W(CO) 5 ] (Fc = Ferrocenyl)

Author(s) -

Ho Feny,

Ganguly Rakesh,

Mathey François

Publication year - 2014

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201402662

Subject(s) - chemistry , ferrocene , thiophene , trapping , phosphinidene , aluminium , ring (chemistry) , medicinal chemistry , stereochemistry , organic chemistry , electrochemistry , ecology , electrode , biology

Aluminum trichloride catalyzes the ring opening of a 1‐chlorophosphirane W(CO) 5 complex and its reaction with thiophene and ferrocene to give the corresponding 1‐(2‐thienyl)‐ and 1‐ferrocenylphosphirane derivatives. The W(CO) 5 complex of the 1‐ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP‐W(CO) 5 ], which is trapped by tolan, trans ‐stilbene, and water.

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