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Activation of a 1‐Chlorophosphirane Complex by Aluminum Trichloride: Generation and Trapping of [Fc‐P‐W(CO) 5 ] (Fc = Ferrocenyl)
Author(s) -
Ho Feny,
Ganguly Rakesh,
Mathey François
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402662
Subject(s) - chemistry , ferrocene , thiophene , trapping , phosphinidene , aluminium , ring (chemistry) , medicinal chemistry , stereochemistry , organic chemistry , electrochemistry , ecology , electrode , biology
Aluminum trichloride catalyzes the ring opening of a 1‐chlorophosphirane W(CO) 5 complex and its reaction with thiophene and ferrocene to give the corresponding 1‐(2‐thienyl)‐ and 1‐ferrocenylphosphirane derivatives. The W(CO) 5 complex of the 1‐ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP‐W(CO) 5 ], which is trapped by tolan, trans ‐stilbene, and water.