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Organic–Inorganic Hybrid Membranes Based on Sulfonated Poly(ether ether ketone) and Tetrabutylphosphonium Bromide Ionic Liquid for PEM Fuel Cell Applications
Author(s) -
Rangasamy Vijay Shankar,
Thayumanasundaram Savitha,
de Greef Niels,
Seo Jin Won,
Locquet JeanPierre
Publication year - 2015
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402558
Subject(s) - membrane , chemistry , ionic liquid , dielectric spectroscopy , chemical engineering , bromide , thermal stability , proton exchange membrane fuel cell , ether , solvent , polymer chemistry , inorganic chemistry , electrochemistry , organic chemistry , engineering , catalysis , biochemistry , electrode
Ionic liquids (ILs), with their inherent ionic conductivity and negligible vapor pressure, can be exploited in proton exchange membrane (PEM) fuel cells for which thermal management is a major problem and the cell operation temperature is limited by the boiling point of water. In this work, sulfonated poly(ether ether ketone) (SPEEK) membranes were modified by the incorporation of tetrabutylphosphonium bromide ([P 4 4 4 4 ]Br) by solvent‐casting. Electrochemical impedance spectroscopy (EIS) was used to study the electrical properties of the modified membranes. Simultaneous TGA and FTIR studies were used to evaluate the thermal stability and chemical structure of the modified membranes, respectively. 1 H NMR spectroscopy was applied to probe the changes in the chemical environment due to the interaction between the ionic liquid and the polymer. Mechanical properties were studied by dynamic mechanical analysis. The temperature‐dependent behavior of the viscosity of the [P 4 4 4 4 ]Br ionic liquid was observed to obey the Vogel–Fulcher–Tammann (VFT) equation, and was correlated to the ion‐conducting properties of the IL‐doped SPEEK membranes.