Mixed‐Metal Oxo Clusters Structurally Derived from Ti 6 O 4 (OR) 8 (OOCR′) 8 | Zendy

Artner Christine | Zendy; Koyun Ayse | Zendy; Czakler Matthias | Zendy; Schubert Ulrich | Zendy

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Mixed‐Metal Oxo Clusters Structurally Derived from Ti 6 O 4 (OR) 8 (OOCR′) 8

Author(s) -

Artner Christine,

Koyun Ayse,

Czakler Matthias,

Schubert Ulrich

Publication year - 2014

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201402499

Subject(s) - chemistry , metal , titanium , crystallography , inorganic chemistry , organic chemistry

The mixed‐metal oxo clusters FeTi 5 O 4 (O i Pr) 4 (OMc) 10 (OMc = methacrylate), Zn 2 Ti 4 O 4 (O i Pr) 2 (OMc) 10 , Cd 4 Ti 2 O 2 (OAc) 2 (OMc) 10 (HO i Pr) 2 , [Ca 2 Ti 4 O 4 (OAc) 2 (OMc) 10 ] n , and [Sr 2 Ti 4 O 4 (OMc) 12 (HOMc) 2 ] n were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti 6 O 4 (OR) 8 (OOCR′) 8 . The Ca and Sr derivatives consist of chains of condensed clusters.

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