Premium
Syntheses and Solid‐State Structures of Et 2 SbTeEt and Et 2 BiTeEt
Author(s) -
Heimann Stefan,
Kuczkowski Andreas,
Bläser Dieter,
Wölper Christoph,
Haack Rebekka,
Jansen Georg,
Schulz Stephan
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402471
Subject(s) - chemistry , solid state , crystallography , intermolecular force , density functional theory , diffraction , single crystal , crystal structure , x ray crystallography , dispersion (optics) , computational chemistry , molecule , optics , organic chemistry , physics
Diethylstibanyl‐ and diethylbismuthanyl telluranes Et 2 MTeEt (M = Sb 1 , Bi 2 ) as well as t Bu 3 Sb ( 3 ) were structurally characterized by single‐crystal X‐ray diffraction. Single crystals of 1 – 3 were grown by using an IR‐laser‐assisted technique. Compounds 1 and 2 form short intermolecular E ··· Te interactions in the solid state, which were further investigated with dispersion‐corrected density functional theory.