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Hydrophilic Pd 0 Complexes Based on Sugars for Efficient Suzuki–Miyaura Coupling in Aqueous Systems
Author(s) -
Tarantino Giulia,
Curcio Massimiliano,
Pica Andrea,
Carpentieri Andrea,
Cucciolito Maria E.,
Ruffo Francesco,
Vitagliano Aldo,
Lega Matteo
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402456
Subject(s) - chemistry , aqueous solution , catalysis , aqueous medium , environmentally friendly , suzuki reaction , coupling (piping) , palladium , combinatorial chemistry , sugar , organic chemistry , nuclear chemistry , mechanical engineering , ecology , engineering , biology
Two classes of hydrophilic Pd 0 complexes containing P,N and N,N sugar‐based ligands were prepared and tested in the Suzuki–Miyaura cross‐coupling reaction under environmentally friendly aqueous conditions. The best catalyst was tolerant towards different substrates, and its activity is comparable with the highest values reported so far for reactions in aqueous media [loading 0.0010 %, turnover frequency (TOF) 3.5 × 104 h –1 ].