Synthesis and Characterization of Cationic Synphos‐Rhodium Complexes | Zendy

Meißner Antje | Zendy; Drexler HansJoachim | Zendy; Keller Sonja | Zendy; Selle Carmen | Zendy; RatovelomananaVidal Virginie | Zendy; Heller Detlef | Zendy

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Synthesis and Characterization of Cationic Synphos‐Rhodium Complexes

Author(s) -

Meißner Antje,

Drexler HansJoachim,

Keller Sonja,

Selle Carmen,

RatovelomananaVidal Virginie,

Heller Detlef

Publication year - 2014

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201402324

Subject(s) - rhodium , chemistry , cationic polymerization , toluene , dimer , medicinal chemistry , acetone , ligand (biochemistry) , stereochemistry , catalysis , polymer chemistry , organic chemistry , receptor , biochemistry

Different types of cationic Rh complexes bearing the Synphos ligand were characterized by NMR and X‐ray analysis for the first time. This set of compounds includes diolefin rhodium precursors [Rh(Synphos)(cod)]BF 4 and [Rh(Synphos)(nbd)]BF 4 , solvate complexes [Rh(Synphos)(MeOH) 2 ]BF 4 , [Rh(Synphos)(acetone) 2 ]BF 4 as well as the toluene complex [Rh(Synphos)(toluene)]BF 4 , trinuclear complexes [Rh 3 (Synphos) 3 (μ 3 ‐OH) 2 ]BF 4 and [Rh 3 (Synphos) 3 (μ 3 ‐Cl) 2 ]BF 4 and arene‐bridged dimer [Rh 2 (Synphos) 2 ](BF 4 ) 2 .

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