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Synthesis and Characterization of Cationic Synphos‐Rhodium Complexes
Author(s) -
Meißner Antje,
Drexler HansJoachim,
Keller Sonja,
Selle Carmen,
RatovelomananaVidal Virginie,
Heller Detlef
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402324
Subject(s) - rhodium , chemistry , cationic polymerization , toluene , dimer , medicinal chemistry , acetone , ligand (biochemistry) , stereochemistry , catalysis , polymer chemistry , organic chemistry , receptor , biochemistry
Different types of cationic Rh complexes bearing the Synphos ligand were characterized by NMR and X‐ray analysis for the first time. This set of compounds includes diolefin rhodium precursors [Rh(Synphos)(cod)]BF 4 and [Rh(Synphos)(nbd)]BF 4 , solvate complexes [Rh(Synphos)(MeOH) 2 ]BF 4 , [Rh(Synphos)(acetone) 2 ]BF 4 as well as the toluene complex [Rh(Synphos)(toluene)]BF 4 , trinuclear complexes [Rh 3 (Synphos) 3 (μ 3 ‐OH) 2 ]BF 4 and [Rh 3 (Synphos) 3 (μ 3 ‐Cl) 2 ]BF 4 and arene‐bridged dimer [Rh 2 (Synphos) 2 ](BF 4 ) 2 .