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Synthesis and Structure of [Et 3 NH][Fe(HL) 2 ] [H 3 L = L ‐2‐(3,5‐Di‐ tert ‐butyl‐2‐hydroxybenzylamino)succinic Acid] and Its Catalytic Activity towards Efficient Photodegradation of Dyes in the Presence of H 2 O 2
Author(s) -
Dasgupta Sohaham,
Atta Sanghamitra,
Singh N. D. Pradeep,
Deb Dibakar,
Kassel W. Scott,
Bhattacharjee Manish
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402314
Subject(s) - chemistry , malachite green , aqueous solution , rhodamine b , photocatalysis , methylene blue , triethylamine , nuclear chemistry , crystal structure , crystal violet , ligand (biochemistry) , medicinal chemistry , stereochemistry , crystallography , catalysis , organic chemistry , medicine , biochemistry , receptor , adsorption , pathology
A new biogenic potentially tetradentate ligand, L ‐2‐(3,5‐di‐ tert ‐butyl‐2‐hydroxybenzylamino)succinic acid, has been synthesized. Upon reaction with FeCl 3 in the presence of triethylamine, it afforded the complex [Et 3 NH][Fe(HL) 2 ] ( 1 ). The complex was structurally characterized and was used for homogeneous photocatalytic degradation of methylene blue (MB), malachite green (MG), crystal violet (CV) and rhodamine B (RhB) under visible‐light irradiation in aqueous solution in the presence of H 2 O 2 .