Premium
A Facile Route for Stabilizing Highly Reactive ArTeCl Species Through the Formation of T‐Shaped Tellurenyl Chloride Adducts: quasi ‐Planar Zwitterionic [HPy*]TeCl 2 and [HPm*]TeCl 2 ; Py* = 2‐pyridyl, Pm* = 2‐(4,6‐dimethyl)pyrimidyl
Author(s) -
Khrustalev Victor N.,
Matsulevich Zhanna V.,
Lukiyanova Julia M.,
Aysin Rinat R.,
Peregudov Alexander S.,
Leites Larissa A.,
Borisov Alexander V.
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402294
Subject(s) - chemistry , adduct , monomer , chloride , molecule , raman spectroscopy , crystallography , hydrochloric acid , salt (chemistry) , inorganic chemistry , organic chemistry , physics , optics , polymer
Two new stable T‐shaped tellurenyl chloride adducts, viz., [HPy*]TeCl 2 ( 1 ) and [HPm*]TeCl 2 ( 2 ) [Py* = 2‐pyridyl, Pm* = 2‐(4,6‐dimethyl)pyrimidyl], act as close chemical analogs of highly unstable monomeric Py*TeCl and Pm*TeCl. The quasi ‐planar zwitterionic structures of 1 and 2 have been studied by experimental (X‐ray diffraction, multinuclear NMR, IR and Raman spectroscopy) and theoretical (DFT and QTAIM) methods. Thus, a novel facile route to stabilize highly reactive Ar*TeCl species (Ar* = N ‐functionalized aryl) by the addition of a hydrochloric acid molecule has been demonstrated.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom