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Luminescent Polymer Films from Simple Processing of Coronene and Europium Precursors in Water
Author(s) -
Planells Miquel,
Klampaftis Efthymios,
Congiu Martina,
Shivanna Ravichandran,
Rao K. Venkata,
Chepelin Oleg,
Jones Anita C.,
Richards Bryce S.,
George Subi J,
Narayan K. S.,
Robertson Neil
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402228
Subject(s) - europium , chemistry , chromophore , phosphorescence , lanthanide , photoluminescence , luminescence , polymer , polyvinyl alcohol , antenna effect , coronene , fluorescence , photochemistry , molecule , polymer chemistry , organic chemistry , materials science , optoelectronics , optics , ion , physics
We describe the preparation and optical characterisation of a coronene tetracarboxylate salt ( CS ) in polyvinyl alcohol (PVA) thin film solutions processed from water, neat or mixed with varying ratios of a europium tris(hexafluoroacetylacetoanto) diaquo complex [Eu(hfac) 3 (H 2 O) 2 ]. Neat CS ‐PVA showed not only well‐defined fluorescence peaks but also a long‐lived phosphorescence emission, persisting for more than 1 second. Interaction between the CS and Eu III molecules, mediated by means of carboxylate coordination to the Eu III , was attained by simple incorporation into the PVA polymer matrix and resulted in energy transfer from the coronone antenna to the europium centre. Under various blend ratios of CS and the Eu III complex, total photoluminescence quantum yields of typically around 30 % were achieved. The straightforward processing of this type of self‐assembled chromophore‐lanthanide system into a luminescent polymer film offers potential for application to other chromophores, lanthanides and polymers.