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Mild Hydrosilylation of Amides by Platinum N‐Heterocyclic Carbene Catalysts
Author(s) -
Pisiewicz Sabine,
Junge Kathrin,
Beller Matthias
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201402083
Subject(s) - chemistry , hydrosilylation , carbene , catalysis , platinum , organic chemistry , combinatorial chemistry , polymer chemistry
The platinum‐catalyzed hydrosilylation of amides to afford amines selectively is reported. By using defined platinum/N‐heterocyclic carbene complexes, the reduction of secondary and tertiary amines takes place under mild conditions.