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Theoretical Investigation of the Controlled Metathesis Reactions of Methylruthenium(II) Complexes with Terminal Acetylenes
Author(s) -
Liu Yuxia,
Chen Guang,
Wang Hongliang,
Bi Siwei,
Zhang Dongju
Publication year - 2014
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201400123
Subject(s) - chemistry , phenylacetylene , acetylide , ruthenium , metathesis , ligand (biochemistry) , moiety , salt metathesis reaction , medicinal chemistry , stereochemistry , catalysis , organic chemistry , polymerization , biochemistry , polymer , receptor
With the help of density functional theory (DFT) calculations, we theoretically investigated and rationalized the controlled metathesis reactions of methylruthenium complex trans ‐[Ru(CH 3 ) 2 (dmpe) 2 ] [dmpe = 1,2‐bis(dimethylphosphanyl)ethane] ( A ) with terminal acetylenes. On the basis of the mechanistic study, two important issues related to the generation of mono‐ and bis‐acetylido Ru complexes have been addressed. One issue is why the formation of bis‐acetylido complex C , trans ‐[Ru(C≡CPh) 2 ] (dmpe) 2 , is more difficult than the formation of mono‐acetylido complex B , trans ‐[Ru(C≡CPh)(CH 3 )(dmpe) 2 ]. A strong d→π*(C≡C) interaction between Ru and the alkynyl in B is believed to weaken π back‐donation of Ru to the phenylacetylene C–H σ* bond, and then makes the phenylacetylene C–H bond difficult to break. The second issue is what role methanol plays in promoting the ligand metathesis between the methyl group in B and one alkynyl moiety in 1,4‐diethynylbenzene to give bis‐acetylido species D , trans ‐[(PhC≡C)Ru(dmpe) 2 (C≡CC 6 H 4 C≡CH)]. The relatively strong proton‐donating ability of methanol was found to be the major reason. The present study is indicative of the controllable synthesis of mono‐ and bis‐acetylido, and even di‐ and trinuclear acetylide‐bridged ruthenium(II) complexes.