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Proton and Electron Transfer to a Polymer‐Supported Nitrido Molybdenum(VI) Complex (Eur. J. Inorg. Chem. 36/2013)
Author(s) -
Wünsche von Leupoldt Anica,
Förster Christoph,
Fiedler Tobias J.,
Bings Nicolas H.,
Heinze Katja
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201390164
Subject(s) - chemistry , molybdenum , protonation , cover (algebra) , electron paramagnetic resonance , electron transfer , intermolecular force , ammonia , proton , photochemistry , polymer chemistry , inorganic chemistry , organic chemistry , ion , molecule , nuclear magnetic resonance , mechanical engineering , physics , quantum mechanics , engineering
The cover picture shows the reactive EPR‐active imido molybdenum(V) intermediate that has been obtained by protonation followed by reduction of the nitrido molybdenum(VI) precursor confined within a polymeric environment. By immobilizing the precursor, its deactivation by intermolecular reactions is prevented. This system models some steps in the final part of the Schrock–Yandulov cycle, which results in the release of ammonia from nitrido complexes. Details are discussed in the article by K. Heinze et al. on p. 6079 ff . For more on the story behind the cover research, see the Cover Profile .