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Extending the Family of N‐Heterocyclic Heavy Carbene Analogues: Synthesis and Crystal and Molecular Structures of MeN[CH 2 C(O)N(R)] 2 Sn (R = Me 2 NCH 2 CH 2 , PhCH 2 , Me 3 CCH 2 ) (Eur. J. Inorg. Chem. 34/2013)
Author(s) -
IovkovaBerends Ljuba,
Seiger Miriam,
Westfeld Thomas,
Hoffmann Alexander,
HerresPawlis Sonja,
Jurkschat Klaus
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201390154
Subject(s) - intramolecular force , chemistry , cover (algebra) , coordination complex , crystallography , crystal structure , stereochemistry , organic chemistry , metal , mechanical engineering , engineering
The cover picture shows cyclic diazastannylenes reported by Hahn et al., Russel et al., Zaitsev et al., and Jurkschat et al., which have intramolecular donor→Sn coordination in common. This coordination enhances the stability of the Sn II compounds to the extent that the compound synthesized at TU Dortmund, shown in the forefront and reported in this issue, is even stable in air. Details are discussed in the article by K. Jurkschat et al. on p. 5836 ff . For more on the story behind the cover research, see the Cover Profile .