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A Solid‐Solution Approach to Mixed‐Metal Metal–Organic Frameworks – Detailed Characterization of Local Structures, Defects and Breathing Behaviour of Al/V Frameworks (Eur. J. Inorg. Chem. 26/2013)
Author(s) -
Kozachuk Olesia,
Meilikhov Mikhail,
Yusenko Kirill,
Schneemann Andreas,
Jee Bettina,
Kuttatheyil Anusree V.,
Bertmer Marko,
Sternemann Christian,
Pöppl Andreas,
Fischer Roland A.
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201390114
Subject(s) - cover (algebra) , metal organic framework , chemistry , metal , characterization (materials science) , structural chemistry , electron paramagnetic resonance , nanotechnology , crystallography , mechanical engineering , organic chemistry , materials science , physics , adsorption , nuclear magnetic resonance , engineering
The cover picture shows correlations (linear as well as non‐linear) between metal ratios and the structure and properties of materials while increasing the complexity of the framework and combining different metals in single‐phased MOFs to give mixed‐metal MOF solid solutions. The applied EPR spectroscopic analysis, in particular, is a powerful tool in these studies to obtain insight into the local metal structures in such complex multicomponent MOF materials and to detect intrinsic structural defects that are not observed (and not expected) in the parent monometallic MOFs. O. K. is acknowledged for designing the cover artwork. Details are discussed in the article by R. A. Fischer et al. on p. 4546 ff . For more on the story behind the cover research, see the Cover Profile .