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Modulation of the Interlayer Structures and Magnetic Behavior of 2D Spin‐Crossover Coordination Polymers [Fe II (L) 2 Pt II (CN) 4 ] (Eur. J. Inorg. Chem. 5‐6/2013)
Author(s) -
Ohtani Ryo,
Arai Masashi,
Ohba Hisayoshi,
Hori Akihiro,
Takata Masaki,
Kitagawa Susumu,
Ohba Masaaki
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201390022
Subject(s) - spin crossover , chemistry , cooperativity , crystallography , polymer , pyridine , coordination polymer , transition metal , flexibility (engineering) , cover (algebra) , spin (aerodynamics) , stereochemistry , condensed matter physics , crystal structure , physics , thermodynamics , mechanical engineering , biochemistry , statistics , mathematics , organic chemistry , catalysis , medicinal chemistry , engineering
The back cover picture shows a toy that models a 3D interdigitate pillared‐layer‐like structure of 2D Hofmann‐type spin‐crossover coordination polymers, { 2 Pt(CN) 4 } {L = 4‐styrylpyridine (stpy) and 4‐(2‐phenylethyl)pyridine (pep)}. These structures are based on 2D layers (colored plates) extended by Pt–CN–CFe linkages with axial coligands stpy and pep (small, colored pieces of wood). In the real structures, we can modify the interlayer packing structure by appropriate choice of coligands having different shape, size, and flexibility, which strongly affects the cooperativity of the spin transition. Details are discussed in the article by S. Kitagawa, M. Ohba et al. on p. 738 ff.