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Allenylidene Complexes Based on Pentacenequinone
Author(s) -
Strinitz Frank,
Waterloo Andreas,
Tucher Johannes,
Hübner Eike,
Tykwinski Rik R.,
Burzlaff Nicolai
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201300759
Subject(s) - chemistry , ruthenium , absorption (acoustics) , metal , crystal structure , crystal (programming language) , photochemistry , electronic structure , crystallography , computational chemistry , organic chemistry , catalysis , optics , programming language , physics , computer science
Stable ruthenium–allenylidene complexes based on pentacenequinone have been synthesized. The complexes show an electronic absorption in the NIR region that arises from forbidden MLCT transitions, as explained by DFT calculations. The crystal structure reveals promising features for the formation of metal‐influenced organic FETs.