An Efficient Homogeneous Chloro–Aluminum–[N 2 O 2 ] Catalyst for the Coupling of Epoxides with Carbon Dioxide | Zendy

Fuchs Monica A. | Zendy; Altesleben Christiane | Zendy; Zevaco Thomas A. | Zendy; Dinjus Eckhard | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

An Efficient Homogeneous Chloro–Aluminum–[N 2 O 2 ] Catalyst for the Coupling of Epoxides with Carbon Dioxide

Author(s) -

Fuchs Monica A.,

Altesleben Christiane,

Zevaco Thomas A.,

Dinjus Eckhard

Publication year - 2013

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201300634

Subject(s) - chemistry , catalysis , cyclohexene , homogeneous catalysis , homogeneous , carbon dioxide , ligand (biochemistry) , carbonate , cyclohexene oxide , aluminium , propylene carbonate , coupling reaction , coupling (piping) , heterogeneous catalysis , inorganic chemistry , organic chemistry , thermodynamics , biochemistry , physics , receptor , electrode , electrochemistry , mechanical engineering , engineering

The coupling reaction of epoxides and CO 2 is in the focus of many research activities in academia as well as in the industry. In this contribution we report on a versatile aluminum‐based homogeneous catalyst utilizing an easy‐to‐synthesize N 2 O 2 ligand system in combination with various cocatalysts, all of them producing pure alternating poly(cyclohexene carbonate)s with M n values in the range 10000–15000 g mol –1 . This system also efficiently catalyzes the formation of propylene carbonate.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research