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Synthesis, Characterization and Luminescence of Gold Complexes Bearing an NHC Ligand Based on the Imidazo[1,5‐ a ]quinolinol Scaffold
Author(s) -
Kriechbaum Margit,
Winterleitner Gerda,
Gerisch Alexander,
List Manuela,
Monkowius Uwe
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201300575
Subject(s) - chemistry , phosphorescence , halide , luminescence , ligand (biochemistry) , moiety , steric effects , crystallography , photochemistry , single crystal , excited state , crystal structure , fluorescence , stereochemistry , inorganic chemistry , biochemistry , physics , receptor , optoelectronics , quantum mechanics , nuclear physics
We report on the synthesis and characterization of an NHC ligand based on the imidazo[1,5‐ a ]quinolinol scaffold. The benzyl‐protected NHC precursor was used for the preparation of the corresponding Ag I , Au I and Au III complexes. The molecular structures of the Au I and Au III halide complexes determined by single‐crystal X‐ray diffraction reveal considerable distortion of the rigid NHC moiety due to steric repulsion between the gold and oxygen atoms. At ambient temperature, the complexes are weakly fluorescent from an intraligand excited state, whereas at 77 K the emission spectra are dominated by intraligand phosphorescence.