Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N‐Heterocyclic Carbene/Thione Donors | Zendy

Slivarichova Miriam | Zendy; Haddow Mairi F. | Zendy; Othman Hafiizah | Zendy; Owen Gareth R. | Zendy

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Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N‐Heterocyclic Carbene/Thione Donors

Author(s) -

Slivarichova Miriam,

Haddow Mairi F.,

Othman Hafiizah,

Owen Gareth R.

Publication year - 2013

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201300106

Subject(s) - carbene , chemistry , hexafluorophosphate , rhodium , ligand (biochemistry) , medicinal chemistry , stereochemistry , coordination complex , ionic liquid , catalysis , organic chemistry , metal , biochemistry , receptor

The N‐heterocyclic carbene NHC/thione ligand precursors 1‐[(3‐R‐2‐thioxo‐2 H ‐imidazol‐1‐yl)methyl]‐3‐R‐2 H ‐imidazol‐2‐ium hexafluorophosphate, [HCS R ]PF 6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CS R )(cod)][PF 6 ] (R = methyl, benzyl; cod = 1,5‐cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.

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