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Self‐Assembly of Arylboronate Esters with Pyridyl Side Chains
Author(s) -
Sheepwash Erin,
Zhou Kai,
Scopelliti Rosario,
Severin Kay
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201300084
Subject(s) - chemistry , monomer , solid state , side chain , polymer , boron , polymer chemistry , crystallization , self assembly , lewis acids and bases , organic chemistry , combinatorial chemistry , catalysis
Abstract Boronate esters that contain N‐donor groups are self‐complementary structures, which can assemble by means of dative boron–nitrogen bonds to form macrocycles or polymers. Herein, we describe the synthesis of dioxaborinanes and benzodioxaboroles containing pyridyl side chains. In the solid state, the dioxaborinanes were found to exist predominantly as monomers. Upon crystallization, aggregation into one‐dimensional polymers was observed, but only for boronate esters that contained electron‐withdrawing groups. The more Lewis acidic benzodioxaboroles, on the other hand, were found to form macrocycles both in solution and in the solid state.