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Structural Conformation and Optical and Electrochemical Properties of Imidazolyl‐Substituted Naphthalenediimide and Its Hg II , Cd II , and Cu II Halide Complexes (Eur. J. Inorg. Chem. 8/2012)
Author(s) -
Jiang JiaJian,
Yan Cheng,
Pan Mei,
Wang Zi,
Deng HaiYing,
He JianRong,
Yang QingYuan,
Fu Lei,
Xu XianFang,
Su ChengYong
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201290017
Subject(s) - chemistry , halide , metallacycle , crystallography , zigzag , ligand (biochemistry) , electrochemistry , stereochemistry , copper , inorganic chemistry , x ray crystallography , electrode , physics , receptor , organic chemistry , biochemistry , geometry , mathematics , diffraction , optics
Abstract The cover picture shows that an “end‐core‐end”‐type NDI‐based ligand could take either trans , L or cis conformations, just like the two pincers of a crab can have different relative positions. Its coordination with Hg II , Cd II , Cu II halides leads to the formation of M 2 L 2 metallocycles, 1D zigzag chains or ML metallocycle structures. Details are discussed in the article by M. Pan, C.‐Y. Su et al. on p. 1171 ff.