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Experimental and Theoretical Studies of Unusual Four‐Membered Metallacycles from Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes with the Sulfurdiimide Me 3 SiN=S=NSiMe 3 (Eur. J. Inorg. Chem. 4/2012)
Author(s) -
Kaleta Katharina,
Ruhmann Martin,
Theilmann Oliver,
Roy Subhendu,
Beweries Torsten,
Arndt Perdita,
Villinger Alexander,
Jemmis Eluvathingal D.,
Schulz Axel,
Rosenthal Uwe
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201290005
Subject(s) - chemistry , trimethylsilyl , acetylene , metallocene , group (periodic table) , cover (algebra) , medicinal chemistry , stereochemistry , organic chemistry , polymerization , mechanical engineering , engineering , polymer
The cover picture shows the skyline of Rostock at night with a titanocene bis(trimethylsilyl)acetylene complex as well as the unusual metallacyclic complex [Cp 2 Ti(η 2 ‐Me 3 SiN=S=NSiMe 3 )], which can readily be obtained from the former complex by reaction with the sulfurdiimide Me 3 SiN=S=NSiMe 3 , rising brightly into the sky. The synthesis and a detailed theoretical study of the structure and bonding of this exotic organometallic compound are described in the article by E. D. Jemmis, A. Schulz, U. Rosenthal et al. on p. 611 ff.