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Cage Metal Complexes: Synthesis, X‐ray Structure, and Spectral and Redox Behavior of the First Hybrid Iron(II) Clathrochelatoscorpionate and Its Pyrazoloxime‐Armed Macrocyclic Intermediate
Author(s) -
Varzatskii Oleg A.,
Kats Menkach Svitlana V.,
Penkova Larysa V.,
Volkov Sergey V.,
Dolganov Alexander V.,
Vologzhanina Anna V.,
Bubnov Yurii N.,
Voloshin Yan Z.
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201201545
Subject(s) - chemistry , cyclic voltammetry , cycloaddition , redox , metal , cage , crystallography , x ray , macrocyclic ligand , electrochemistry , polymer chemistry , stereochemistry , inorganic chemistry , organic chemistry , catalysis , electrode , physics , mathematics , combinatorics , quantum mechanics
Cycloaddition of a new pyrazoloxime to macrocyclic iron(II) bis(α‐benzyldioximate) unexpectedly gave a mixture of the first hybrid clathrochelatoscorpionate and its pyrazoloxime‐armed macrocyclic intermediate, which were characterized by X‐ray crystallography, spectroscopy, and cyclic voltammetry.