Oxidation of Carbene‐Derived Selenium Diiodide with Silver Tetrafluoroborate – Isolation of Iodonium Ion Complexes with Selones | Zendy

Manjare Sudesh T. | Zendy; Singh Harkesh B. | Zendy; Butcher Ray J. | Zendy

Premium

Oxidation of Carbene‐Derived Selenium Diiodide with Silver Tetrafluoroborate – Isolation of Iodonium Ion Complexes with Selones

Author(s) -

Manjare Sudesh T.,

Singh Harkesh B.,

Butcher Ray J.

Publication year - 2013

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201201238

Subject(s) - chemistry , tetrafluoroborate , carbene , adduct , supramolecular chemistry , chloroform , selenium , ion , tellurium , crystal structure , decomposition , medicinal chemistry , photochemistry , inorganic chemistry , polymer chemistry , organic chemistry , catalysis , ionic liquid

The oxidation reactions of diiodoselones 10a and 10b with silver tetrafluoroborate afford linear complexes of iodonium ions with selones 13a and 13b . The decomposition of the tellurium tetraiodide adduct with benzimidazolin‐2‐selone ( 12 ) in chloroform also affords a similar iodonium ion complex 13c . Crystal structure analysis of 13a – 13c shows interesting supramolecular formation by C–H ··· F, C–H ··· Br, C–H ··· I, Se ··· π, and I ··· π interactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research