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Tin‐Mediated Route to Polytungstates of Rh II and Pd II
Author(s) -
Sokolov Maxim N.,
Kalinina Irina V.,
Peresypkina Eugenia V.,
Moroz Nikolay K.,
Naumov Dmitry Yu.,
Fedin Vladimir P.
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - Slovenian
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201201162
Subject(s) - chemistry , thermogravimetric analysis , tin , spectroscopy , rhodium , nuclear magnetic resonance spectroscopy , crystallography , nuclear chemistry , stereochemistry , catalysis , organic chemistry , physics , quantum mechanics
Three polyoxotungstates of Sn II , Pd II , and Rh II , Na 8 [H 2 SnW 12 O 42 ] · n H 2 O [ 1 , n = 22.75 ( 1a ) and n = 31.10 ( 1b )], Na 2 K(H)[Pd(H 2 O) 4 ][H 2 W 12 O 48 {Pd(H 2 O) 3 } 2 ] · 10H 2 O ( 2 ), and Na 8 [Rh 2 (H 2 O) 2 (W 5 O 18 ) 2 ] · 21.25H 2 O ( 3 ) were obtained. The complexes were characterized by X‐ray analysis, solid‐state 1 H NMR spectroscopy, IR spectroscopy, thermogravimetric analysis, and elemental analysis.