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Perpendicular versus Coplanar Conformation of the SeCl 2 Moiety in T‐Shaped Selenyl Chloride Adducts – Propeller‐Like Free Rotation in Solution
Author(s) -
Khrustalev Victor N.,
Ismaylova Sheyda R.,
Aysin Rinat R.,
Matsulevich Zhanna V.,
Osmanov Vladimir K.,
Peregudov Alexander S.,
Borisov Alexander V.
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201201021
Subject(s) - chemistry , moiety , adduct , raman spectroscopy , perpendicular , chloride , ab initio , crystallography , nuclear magnetic resonance spectroscopy , propeller , double bond , computational chemistry , stereochemistry , polymer chemistry , organic chemistry , geometry , physics , mathematics , optics , marine engineering , engineering
The structures of two new T‐shaped selenyl chloride adducts studied by experimental (multinuclear NMR, IR, and Raman spectroscopy and X‐ray diffraction analysis) and theoretical (ab initio and DFT quantum chemical calculations) methods clearly demonstrate the possibility of propeller‐like free rotation of the SeCl 2 moiety around the C–Se bond and indicate the absence of any significant double‐bond character.