A Salicylaldoxime [Mn 12 ] Complex with an Unprecedented [Mn III  4 Mn II  8 (μ‐OCH 3 ) 4 ] Core | Zendy

Hołyńska Małgorzata | Zendy; Clérac Rodolphe | Zendy; Dehnen Stefanie | Zendy

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A Salicylaldoxime [Mn 12 ] Complex with an Unprecedented [Mn III 4 Mn II 8 (μ‐OCH 3 ) 4 ] Core

Author(s) -

Hołyńska Małgorzata,

Clérac Rodolphe,

Dehnen Stefanie

Publication year - 2012

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201200920

Subject(s) - manganese , antiferromagnetism , chemistry , crystallography , ground state , oxidation state , inorganic chemistry , condensed matter physics , physics , metal , atomic physics , organic chemistry

A mixed‐valent [Mn 12 ] complex with an unprecedented [Mn III 4 Mn II 8 (μ‐OCH 3 ) 4 ] core was obtained by oxidation of MnCl 2 in the presence of salicylaldoxime (saoH 2 ). This complex adopts a rare topology based on a central [Mn II 4 ] cage decorated by four dinuclear [Mn II –Mn III ] motifs. Studies of the magnetic properties show the presence of strong intracomplex antiferromagnetic interactions and suggest an S T = 2 spin ground state.

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