Crystal Structure and Magnetic Properties of a Dinuclear High‐Spin Iron(III) Complex with Face‐to‐Face Bis(Salen)‐Type Ligands | Zendy

Ishikawa Ryuta | Zendy; Breedlove Brian K. | Zendy; Yamashita Masahiro | Zendy

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Crystal Structure and Magnetic Properties of a Dinuclear High‐Spin Iron(III) Complex with Face‐to‐Face Bis(Salen)‐Type Ligands

Author(s) -

Ishikawa Ryuta,

Breedlove Brian K.,

Yamashita Masahiro

Publication year - 2013

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201200914

Subject(s) - chemistry , butane , schiff base , crystal structure , ligand (biochemistry) , crystallography , imidazole , spin (aerodynamics) , crystal (programming language) , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , engineering , aerospace engineering , programming language , computer science

Synthesis and crystal structure of the dinuclear complex threo ‐[Fe III 2 (saltab)(Him) 4 ](ClO 4 ) 2 · 2MeOH ( 1 ) {H 4 saltab = (2 R ,3 S )‐1,2,3,4‐tetrakis(salicylideneamino)butane, a bis(salen)‐type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high‐spin state over the whole temperature region.

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