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Crystal Structure and Magnetic Properties of a Dinuclear High‐Spin Iron(III) Complex with Face‐to‐Face Bis(Salen)‐Type Ligands
Author(s) -
Ishikawa Ryuta,
Breedlove Brian K.,
Yamashita Masahiro
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201200914
Subject(s) - chemistry , butane , schiff base , crystal structure , ligand (biochemistry) , crystallography , imidazole , spin (aerodynamics) , crystal (programming language) , stereochemistry , organic chemistry , catalysis , receptor , biochemistry , engineering , aerospace engineering , programming language , computer science
Synthesis and crystal structure of the dinuclear complex threo ‐[Fe III 2 (saltab)(Him) 4 ](ClO 4 ) 2 · 2MeOH ( 1 ) {H 4 saltab = (2 R ,3 S )‐1,2,3,4‐tetrakis(salicylideneamino)butane, a bis(salen)‐type Schiff base ligand, and Him = imidazole} are reported. The magnetic behavior of 1 showed that it was in a high‐spin state over the whole temperature region.