Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP | Zendy

Suffren Yan | Zendy; GautierLuneau Isabelle | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP

Author(s) -

Suffren Yan,

GautierLuneau Isabelle

Publication year - 2012

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201200792

Subject(s) - acentric factor , chemistry , iodate , crystallography , nonlinear optical , crystal structure , infrared spectroscopy , infrared , bond length , hydrothermal synthesis , diffraction , optical materials , potassium titanyl phosphate , powder diffraction , single crystal , hydrothermal circulation , optics , inorganic chemistry , optoelectronics , materials science , nonlinear system , organic chemistry , chemical engineering , laser , physics , quantum mechanics , iodide , engineering

A new nonlinear compound, TiO(IO 3 ) 2 , was synthesized by the hydrothermal method and characterized by single‐crystal X‐ray diffraction. It crystallizes in the acentric Cmc 2 1 space group with the following lattice parameters: a = 10.222(1) Å, b = 8.254(1) Å, c = 7.277(1) Å, and V = 613.98(13) Å 3 . The structure has alternating Ti–O bond lengths, short [Ti–O 1.733(12) Å, titanyl bond] and long [Ti–O 2.113(12) Å], as observed in the KTiOPO 4 (KTP) material. IR spectroscopy and NLO efficiency studies on a powder sample suggest that TiO(IO 3 ) 2 is a good potential NLO material.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research