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4,4′,5,5′‐Tetrakis(guanidinyl)binaphthyl – Synthesis and Properties of Two Redox‐Active Ligands and Oxidative C–C Coupling to Perylene Derivatives
Author(s) -
Wiesner Sven,
Ziesak Alexandra,
Reinmuth Matthias,
Walter Petra,
Kaifer Elisabeth,
Wadepohl Hubert,
Himmel HansJörg
Publication year - 2013
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201200784
Subject(s) - chemistry , perylene , redox , oxidative coupling of methane , oxidative phosphorylation , zinc , photochemistry , polymer chemistry , stereochemistry , organic chemistry , molecule , catalysis , biochemistry
We report the synthesis and properties of the new redox‐active ligands 4,4′,5,5′‐tetrakis(tetramethylguanidinyl)binaphthyl and 4,4′,5,5′‐tetrakis( N , N′ ‐dimethylethyleneguanidinyl)binaphthyl. The first dinuclear zinc complexes were prepared. Oxidative C–C coupling of these compounds leads to perylene derivatives.