Chromate‐Mediated One‐Step Quantitative Transformation of PW 12  into P 2 W 20  Polyoxometalates | Zendy

Bajpe Sneha R. | Zendy; Breynaert Eric | Zendy; Robeyns Koen | Zendy; Houthoofd Kristof | Zendy; Absillis Gregory | Zendy; Mustafa Danilo | Zendy; ParacVogt Tatja. | Zendy; Maes Andre | Zendy; Martens Johan A. | Zendy; Kirschhock Christine E. A. | Zendy

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Chromate‐Mediated One‐Step Quantitative Transformation of PW 12 into P 2 W 20 Polyoxometalates

Author(s) -

Bajpe Sneha R.,

Breynaert Eric,

Robeyns Koen,

Houthoofd Kristof,

Absillis Gregory,

Mustafa Danilo,

ParacVogt Tatja.,

Maes Andre,

Martens Johan A.,

Kirschhock Christine E. A.

Publication year - 2012

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201200440

Subject(s) - chemistry , chromate conversion coating , aqueous solution , extended x ray absorption fine structure , electron paramagnetic resonance , hydrolysis , spectroscopy , crystallography , inorganic chemistry , analytical chemistry (journal) , nuclear chemistry , absorption spectroscopy , chromium , nuclear magnetic resonance , organic chemistry , physics , quantum mechanics

The addition of H 3 PW 12 O 40 to an aqueous solution of K 2 CrO 4 led to the hydrolysis of [PW 12 O 40 ] 3– with its quantitative conversion into K 13 [KP 2 W 20 O 72 ]. K 13 [KP 2 W 20 O 72 ] in these chromate‐containing solutions was characterized by 183 W and 31 P NMR, EXAFS, SAXS, and EPR spectroscopy.

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