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Synthesis of Silyl–Molybdenum Complexes Connected by a 1,1′‐Metallocenylene Unit and Their Electrochemical Properties (Eur. J. Inorg. Chem. 36/2011)
Author(s) -
Itazaki Masumi,
Ichimura Akio,
Nakazawa Hiroshi
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201190108
Subject(s) - chemistry , electrochemistry , molybdenum , silylation , cyclic voltammetry , unit (ring theory) , crystal structure , inorganic chemistry , crystallography , polymer chemistry , organic chemistry , catalysis , electrode , mathematics education , mathematics
The cover picture shows the results of the electrochemical investigation (cyclic voltammetry) of various silylferrocene derivatives and the crystal structure of [{Cp*(CO) 3 MoSiMe 2 C 5 H 4 } 2 Fe]. These results reveal that the HSiMe 2 and Cp*Mo(CO) 3 (SiMe 2 ) groups have electron‐withdrawing and electron‐donating properties, respectively. Details of the synthesis, the electrochemical properties and the first structurally characterized silyl–molybdenum complexes connected by a 1,1′‐metallocenylene unit are discussed in the article by H. Nakazawa et al. on page 5496 ff.