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Mechanistic Insights into the Palladium‐Catalysed Asymmetric Phosphination of Cyclohexenyl Triflate (Eur. J. Inorg. Chem. 16/2011)
Author(s) -
Julienne Delphine,
Delacroix Olivier,
Lohier JeanFrançois,
de OliveiraSantos Jana Sopkova,
Gaumont AnnieClaude
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201190045
Subject(s) - chemistry , trifluoromethanesulfonate , catalytic cycle , catalysis , palladium , phosphide , boron , medicinal chemistry , computational chemistry , stereochemistry , organic chemistry
The cover picture shows the catalytic cycle of the Pd‐catalysed asymmetric phosphination involving an achiral alkenyl triflate and a racemic boron phosphide. A mechanistic study illustrated by the gears in the background allowed us to identify each main intermediate of this catalytic cycle. To proceed, tools such as 31 P NMR spectroscopy and X‐ray crystallography were used. Details are discussed in the article by A.‐C. Gaumont et al. on p. 2489 ff.