Premium
N‐Doped Nb 2 O 5 Sensitized by Carbon Nitride Polymer – Synthesis and High Photocatalytic Activity under Visible Light
Author(s) -
Wang Xu,
Chen Gang,
Zhou Chao,
Yu Yaoguang,
Wang Gang
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201101285
Subject(s) - photocatalysis , x ray photoelectron spectroscopy , photodegradation , chemistry , rhodamine b , carbon nitride , diffuse reflectance infrared fourier transform , visible spectrum , scanning electron microscope , graphitic carbon nitride , photochemistry , nuclear chemistry , catalysis , materials science , chemical engineering , organic chemistry , optoelectronics , engineering , composite material
Abstract N‐doped Nb 2 O 5 sensitized by carbon nitride polymer (CNNO) was synthesized as a yellowish powder by using urea as a carbon–nitrogen precursor. CNNO was tested as a catalyst for the visible‐light‐responsive photodegradation of dyes. HNbO 3 , one of the precursors of CNNO, was obtained from LiNbO 3 by a H + –Li + ion‐exchange reaction and then pyrolyzed at 400 °C to produce a Nb 2 O 5 substrate. The photocatalytic activities of as‐prepared samples were evaluated by the degradation of Rhodamine B (RhB) under Xe lamp irradiation ( λ > 400 nm), for which the photocatalysts showed relatively high activities. XRD, thermogravimetry and differential scanning calorimetry (TG–DSC), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDS), TEM, X‐ray photoelectron spectroscopy (XPS), UV/Vis diffuse reflectance spectroscopy (DRS), and Brunauer–Emmett–Teller (BET) measurements were utilized to explore the characteristics of the obtained samples. The results demonstrated that the surface of Nb 2 O 5 was successfully coated, as a semitransparent layer of CN polymer surrouding the dark substrate was observed. UV/Vis DRS showed that the absorption edges of CNNO were shifted remarkably to the visible region relative to those of naked Nb 2 O 5 . These results revealed that the significantly enhanced photocatalytic activities of the CNNO samples originate from the CN polymer. The coating led to an efficient electron transfer between the CN polymer, which acted as a photosensitizer, and the N‐doped Nb 2 O 5 . The degradation mechanism that underlies the excellent photocatalytic activity of CNNO was discussed extensively.