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Synthesis of Stable Ruthenium Olefin Metathesis Catalysts with Mixed Anionic Ligands
Author(s) -
Gawin Rafał,
Grela Karol
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201101048
Subject(s) - chemistry , ruthenium , catalysis , olefin metathesis , ligand (biochemistry) , iodide , carboxylate , metathesis , salt metathesis reaction , combinatorial chemistry , olefin fiber , organic chemistry , polymer chemistry , receptor , biochemistry , polymer , polymerization
A series of ruthenium carboxylate complexes that contain two different anionic ligands was prepared. The complexes that bear iodide ligands exhibit remarkable chemical stability. Such complexes have a diminished tendency to undergo anionic ligand exchange and can be activated byvarious acids to form catalysts, which are active in olefinmetathesis reactions.