Cyclopentadienyl–NHC Iron Complexes for Solvent‐Free Catalytic Hydrosilylation of Aldehydes and Ketones | Zendy

Bézier David | Zendy; Jiang Fan | Zendy; Roisnel Thierry | Zendy; Sortais JeanBaptiste | Zendy; Darcel Christophe | Zendy

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Cyclopentadienyl–NHC Iron Complexes for Solvent‐Free Catalytic Hydrosilylation of Aldehydes and Ketones

Author(s) -

Bézier David,

Jiang Fan,

Roisnel Thierry,

Sortais JeanBaptiste,

Darcel Christophe

Publication year - 2012

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201100762

Subject(s) - hydrosilylation , chemistry , cyclopentadienyl complex , catalysis , solvent , photochemistry , polymer chemistry , organic chemistry

Seven cyclopentadienyl–NHC piano‐stool iron complexes were prepared and studied in the catalytic hydrosilylation of aldehydes and ketones under visible light irradiation. A significant acceleration of the rate was observed when the reactions were carried out under solvent‐free conditions. Single‐crystal X‐ray structural analyses were performed for complexes 5 and 7 .

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