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Cyclopentadienyl–NHC Iron Complexes for Solvent‐Free Catalytic Hydrosilylation of Aldehydes and Ketones
Author(s) -
Bézier David,
Jiang Fan,
Roisnel Thierry,
Sortais JeanBaptiste,
Darcel Christophe
Publication year - 2012
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201100762
Subject(s) - hydrosilylation , chemistry , cyclopentadienyl complex , catalysis , solvent , photochemistry , polymer chemistry , organic chemistry
Seven cyclopentadienyl–NHC piano‐stool iron complexes were prepared and studied in the catalytic hydrosilylation of aldehydes and ketones under visible light irradiation. A significant acceleration of the rate was observed when the reactions were carried out under solvent‐free conditions. Single‐crystal X‐ray structural analyses were performed for complexes 5 and 7 .