HP‐KB 3 O 5  Highlights the Structural Diversity of Borates: Corner‐Sharing BO 3 /BO 4  Groups in Combination with Edge‐Sharing BO 4  Tetrahedra | Zendy

Neumair Stephanie C. | Zendy; Vanicek Stefan | Zendy; Kaindl Reinhard | Zendy; Többens Daniel M. | Zendy; Martineau Charlotte | Zendy; Taulelle Francis | Zendy; Senker Jürgen | Zendy; Huppertz Hubert | Zendy

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HP‐KB 3 O 5 Highlights the Structural Diversity of Borates: Corner‐Sharing BO 3 /BO 4 Groups in Combination with Edge‐Sharing BO 4 Tetrahedra

Author(s) -

Neumair Stephanie C.,

Vanicek Stefan,

Kaindl Reinhard,

Többens Daniel M.,

Martineau Charlotte,

Taulelle Francis,

Senker Jürgen,

Huppertz Hubert

Publication year - 2011

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201100618

Subject(s) - chemistry , tetrahedron , boron , enhanced data rates for gsm evolution , crystallography , solid state , nanotechnology , telecommunications , materials science , organic chemistry , computer science

The new compound HP‐KB 3 O 5 was synthesized under high‐pressure/high‐temperature conditions. It is the first compound exhibiting all three possible conjunctions simultaneously: corner‐sharing BO 3 groups, corner‐sharing BO 4 units, as well as edge‐sharing BO 4 tetrahedra. Calculations of harmonic vibrational frequencies and 11 B solid‐state NMR measurements were performed for the first time with a compound exhibiting edge‐sharing BO 4 tetrahedra.

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