Premium
HP‐KB 3 O 5 Highlights the Structural Diversity of Borates: Corner‐Sharing BO 3 /BO 4 Groups in Combination with Edge‐Sharing BO 4 Tetrahedra
Author(s) -
Neumair Stephanie C.,
Vanicek Stefan,
Kaindl Reinhard,
Többens Daniel M.,
Martineau Charlotte,
Taulelle Francis,
Senker Jürgen,
Huppertz Hubert
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201100618
Subject(s) - chemistry , tetrahedron , boron , enhanced data rates for gsm evolution , crystallography , solid state , nanotechnology , telecommunications , materials science , organic chemistry , computer science
The new compound HP‐KB 3 O 5 was synthesized under high‐pressure/high‐temperature conditions. It is the first compound exhibiting all three possible conjunctions simultaneously: corner‐sharing BO 3 groups, corner‐sharing BO 4 units, as well as edge‐sharing BO 4 tetrahedra. Calculations of harmonic vibrational frequencies and 11 B solid‐state NMR measurements were performed for the first time with a compound exhibiting edge‐sharing BO 4 tetrahedra.