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Graphical Abstract: Eur. J. Inorg. Chem. 25/2010
Publication year - 2010
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201090076
Subject(s) - chemistry , histidine , aqueous solution , stereochemistry , peptide , cover (algebra) , crystal structure , crystallography , enzyme , biochemistry , organic chemistry , mechanical engineering , engineering
The cover picture shows the crystal structures of two complexes that were prepared from aqueous reactions of histidine‐based ligands with Re(CO) 3 (H 2 O) 3 + and serve as models of 99m Tc(CO) 3 + /His‐tag protein complexes. The complexes, similar to those found in certain enzymes, show unexpected peptide carboxamido‐N donor bonds that underscore the stability of the labeled His‐tag proteins as discussed in the Short Communication by R. S. Herrick, C. J. Ziegler et al. on p. 3905 ff. Artwork: Christopher J. Ziegler.