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Non‐Oxido Mixed‐Valence Mn II 6 Mn III 4 Cluster with Benzoate, Triethanolamine and Phosphonate Bridging Ligands (Eur. J. Inorg. Chem. 20/2010)
Author(s) -
DendrinouSamara Catherine,
Muryn Christopher A.,
Tuna Floriana,
Winpenny Richard E. P.
Publication year - 2010
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201090057
Subject(s) - chemistry , phosphonate , valence (chemistry) , triethanolamine , crystallography , ion , cluster (spacecraft) , crystal structure , stereochemistry , inorganic chemistry , organic chemistry , analytical chemistry (journal) , computer science , programming language
The cover picture shows a mixed‐valence {Mn 10 } cage, which can be regarded as an analogue of 24‐metallacrown‐10. The cage is a host for three potassium ions and crystallises as a cation; benzoate anions link the cages into a 1D polymer within the crystal. Details are discussed in the article by C. Dendrinou‐Samara, R. E. P. Winpenny et al. on p. 3097 ff. The authors thank Mrs. A. Samara for the artwork of the cover picture.