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Titanacalixarenes in Homogeneous Catalysis: Synthesis, Conformation and Catalytic Activity in Ethylene Polymerisation (Eur. J. Inorg. Chem. 9/2010)
Author(s) -
Espinas Jeff,
Darbost Ulrich,
Pelletier Jeremie,
Jeanneau Erwan,
Duchamp Christian,
Bayard François,
Boyron Olivier,
Broyer JeanPierre,
ThivolleCazat Jean,
Basset JeanMarie,
Taoufik Mostafa,
Bonnamour Isabelle
Publication year - 2010
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201090022
Subject(s) - chemistry , calixarene , catalysis , titanium , homogeneous , ligand (biochemistry) , polyethylene , ethylene , polymerization , homogeneous catalysis , polymer chemistry , combinatorial chemistry , organic chemistry , molecule , receptor , polymer , biochemistry , physics , thermodynamics
The cover picture shows that improved titanium catalysts based on calixarene ligands can display high activity for the production of ultra‐high‐molecular‐weight polyethylene (UHMWPE). Both the coordination mode of the titanium and the conformation of the calixarene ligand have been found to be significant for the catalytic performance. Details are discussed in the article by M. Taoufik, I. Bonnamour et al. on p. 1349 ff.

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