{Rh(P i Bu 3 ) 2 } +  Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I  – An Experimental Approach | Zendy

Woolf Anthony | Zendy; Chaplin Adrian B. | Zendy; McGrady John E. | Zendy; Alibadi Muhsen A. M. | Zendy; Rees Nicholas | Zendy; Draper Sylvia | Zendy; Murphy Frances | Zendy; Weller Andrew S. | Zendy

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{Rh(P i Bu 3 ) 2 } + Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I – An Experimental Approach

Author(s) -

Woolf Anthony,

Chaplin Adrian B.,

McGrady John E.,

Alibadi Muhsen A. M.,

Rees Nicholas,

Draper Sylvia,

Murphy Frances,

Weller Andrew S.

Publication year - 2011

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201001263

Subject(s) - chemistry , triphenylene , pyrene , naphthalene , coronene , benzene , anthracene , hexamethylbenzene , crystal structure , crystallography , stereochemistry , molecule , photochemistry , organic chemistry

We report the synthesis, structural characterisation andsolution‐phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12‐electron {Rh(P i Bu 3 ) 2 } + fragment. Crystal structures of this fragment with benzene, naphthalene, anthracene, pyrene, triphenylene and coronene are described, alongside their solution NMR spectroscopic data. The ligands map out a systematic increase in size of the aromatic subunit, and represent an approach to the limiting case of coordination to a graphene surface. The solid‐state and solution structures of a {Rh(COD)} + fragment coordinated to a hexa‐ peri ‐hexabenzocoronene are also reported.

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