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Synthesis, Spectroscopic and Structural Studies on Vanadium(V) Periodates
Author(s) -
Hector Andrew L.,
Levason William
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201001242
Subject(s) - chemistry , vanadium , octahedron , extended x ray absorption fine structure , crystallography , amorphous solid , crystallization , absorption spectroscopy , absorption (acoustics) , square pyramidal molecular geometry , k edge , inorganic chemistry , crystal structure , organic chemistry , physics , quantum mechanics , acoustics
Reactions of V 2 O 5 or NH 4 VO 3 with periodic acid under basic conditions followed by acidification result in precipitates of general formula M 5 V 4 I 2 O 19 (OH) · n H 2 O (M = Na, n = 10; M = K, n = 5; M = Rb, n = 4; M = Cs, n = 3; M = NH 4 , n = 11). These are amorphous, and attempts at crystallisation failed, but spectroscopic measurements and analysis show similar features and compositions throughout this series of compounds. V and I K‐edge extended X‐ray absorption fine structure (EXAFS) spectra show a polymeric structure containing edge‐linked octahedral periodate and square‐pyramidal vanadyl groups.