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Synthesis and Some Chemical Properties of a 1,2λ 3 σ 3 ‐Thiaphosphirane
Author(s) -
Turcheniuk Kostiantyn V.,
Rozhenko Alexander B.,
Shevchenko Igor V.
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201001192
Subject(s) - chemistry , chemical stability , ring (chemistry) , sulfur , chemical bond , computational chemistry , organic chemistry
A rare example of the addition of sulfur to a phosphaalkene double bond leading to 1,2λ 3 ,σ 3 ‐thiaphosphirane 4 is described. The relative accessibility of this compound has allowed the study of some of the chemical properties of the thiaphosphirane ring. The thermodynamic stability of 1,2λ 3 ,σ 3 ‐thiaphosphiranes compared with λ 5 ,σ 3 ‐phosphoranes has been studied by DFT calculations.
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